Peresters, their preparation and use as polymerization initiator

Organic compounds -- part of the class 532-570 series – Organic compounds – Compounds having the group -c

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C07C17918

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048597945

ABSTRACT:
New dialkyl esters of monoperoxyoxalic acid which have a tertiary alkyl group in the perester part of the molecule while the other alkyl group is a long-chain, primary alkyl group. The compounds give rise to radicals at heating and are useful as initiators for the polymerization of ethylenically unsaturated monomers, particularly for the polymerization of vinyl chloride.

REFERENCES:
patent: 2608571 (1952-08-01), Rust
Chem. Abstracts, 104:225267h, "Initiation of Radical Reactions by Thermal . . . " (1986).

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