Perchlorate destruction

Catalyst – solid sorbent – or support therefor: product or process – Regenerating or rehabilitating catalyst or sorbent – Treating with a liquid or treating in a liquid phase,...

Reexamination Certificate

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C502S027000

Reexamination Certificate

active

07399725

ABSTRACT:
Perchlorate is removed and effectively destroyed in devices and methods that employ a eluting solvent in which the anion of an acid solubilizes Ti (III), which may be electrochemically generated or added in situ. Using such solvents, destruction of perchlorate is unexpectedly and several orders of magnitude faster than using solvents without solubilizing acids. In most preferred aspects, the solubilizing acid is methane sulfonic acid and/or sulfamic acid, and Ti (III) is electrochemically generated. Perchlorate destruction will then result in formation of Ti (IV), which may be present in the eluent in a subsequent elution.

REFERENCES:
patent: 5266173 (1993-11-01), Bandlish et al.
patent: 6358396 (2002-03-01), Gu et al.

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