Peptide derivatization method to increase fragmentation...

Chemistry: analytical and immunological testing – Nuclear magnetic resonance – electron spin resonance or other...

Reexamination Certificate

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C436S086000, C436S089000

Reexamination Certificate

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07838303

ABSTRACT:
A method of facilitating analysis of a peptide in a mass spectrometer comprising derivatizing the C-terminus of the peptide with an amino acid residue via a reaction with a carbodiimide reagent, yielding a derivative peptide, ionizing the derivative peptide with a double charge, and fragmenting the ionized derivative peptide in a mass spectrometry system, wherein binary fragments of the ionized derivative each include a charge, facilitating sequence analysis of the peptide.

REFERENCES:
patent: 2003/0119069 (2003-06-01), Schneider
patent: 2003/0153007 (2003-08-01), Chen et al.
patent: 2004/0161795 (2004-08-01), Marto
patent: 2004/0209251 (2004-10-01), Schneider
Carter “Vonjugate of Peptodes to Carrier Protein via Carbodiimide” from “The Protein Protocols Handbook”, 1996, p. 693.
GB Search Report, Nov. 6, 2007.
T. Nakazawa et al., “Enhanced responses in matrix-assisted laser desorption/ionization mass spectrometry of peptides derivatized with arginine via a C-terminal oxazolone”, Rapid Communications in Mass Spectrometry, vol. 18, pp. 799-807 (2004).

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