Pentacyclic hydrocarbon compound and halogenated pentacyclic hyd

Details Pentacyclic hydrocarbon compound and halogenated pentacyclic hyd Pentacyclic hydrocarbon compound and halogenated pentacyclic hyd

1995-01-20

1997-03-04

Caldarola, Glenn A.

Chemistry of hydrocarbon compounds

Alicyclic compound synthesis

Polycyclic product

585360, C07C40300, C07C 276, C07C 1328

Patent

active

056081316

ABSTRACT:
A process for the preparation of the compound of the formula ##STR1## comprising dimerizing norbornadiene in the presence of N-methylpiperidine and a combined catalyst of (1,5-cyclooctadiene)(1,3,5-cyclooctatriene)-ruthenium and N,N-dimethylacrylamide.

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patent: 4229612 (1980-10-01), Hall, Jr. et al.
patent: 4275254 (1981-06-01), Schneider et al.
P. Eaton et al., "The Peristylane System", J. Am. Chem. Soc., vol. 94, No. 3, pp. 1014-1016.
P. Eaton et al., "Synthesis of Peristylane and the acs-(Cs)-C14-Tetraquinane, C14-Pentaquinane, and Norperistylane Systems", J. Am. Chem. Soc., vol. 99, No. 8, pp. 2751-2766.
T. Mitsudo et al., "Ruthenium Complex-catalysed Dimerization of Norbornadiene to Pentacyclotetradecadiene", J. Chem. Soc., Chem. Commun., pp. 435-436.

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