Peelably sealed packaging

Stock material or miscellaneous articles – Web or sheet containing structurally defined element or... – Adhesive outermost layer

Reexamination Certificate

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Details

C428S500000, C428S515000, C428S513000, C428S040100

Reexamination Certificate

active

06630237

ABSTRACT:

BACKGROUND OF THE INVENTION
The present invention relates to peelably sealed packaging, and more particularly to peelable films useful to incorporate in peelably sealed packaging.
Peelably sealed, “easy-open” packaging is used in a variety of food and non-food packaging applications to provide packaging that is easy for the consumer to open without having to tear the packaging. Peelably sealed packaging may take several forms. For example, a flexible film lidding or lid stock material may be peelably adhered to a rigid tray, tub, or container. Alternatively, the easy-open packaging may incorporate a peelable seal between a combination of one or more of flexible films, webs, substrates, or supports. Examples of this alternative include thermoforming and vacuum skin packaging methods known in the art. For example, the lower web or support (e.g., “formed web”) may be heated and deep-drawn to form a receptacle for the item to be packaged. Once the item is placed on the support, the upper web (e.g., “non-formed web”) is drawn over the item and peelably sealed to the peripheral edges of the support. The seal may be formed using heated sealing bars, platens, or frames to apply heat and pressure to the top and bottom webs in the seal area.
Other types of easy-open packaging may be formed using vertical-form-fill-seal (VFFS) or horizontal-form-fill-seal (HFFS) methods known in the art to form a pouch or bag containing the packaged product. In such alternatives, the peelable film or web may in effect be sealed to itself (i.e., the same type of film material may form both the top and bottom web of the packaging).
The layer of the peelable film that primarily facilitates the easy-open, peelable seal is known as the “peelable layer” or “separation layer.” If the film is a mono-layer film, then the film itself may be considered the peelable layer. If the peelable layer is an outer layer of a multi-layer film, then the peelable layer may be a sealant layer (e.g., heat-seal layer) of the film.
A peelable layer may also be an internal layer of a multi-layer film. In such an arrangement, one or more layers of a film may be hand peeled away (i.e., delaminated) from the remaining layers of the film, which remain attached to the substrate. This design may be used, for example, to peel away oxygen-impermeable layers of a film from the oxygen-permeable layers of the film at a desired time after the original construction of the packaging. Such a design is described, for example, in U.S. Pat. No. 5,919,547 issued Jul. 6, 1997 to Kocher, which is incorporated herein in its entirety by reference.
To open an easy-open packaging, the consumer simply grasps a portion of one web and pulls or “peels” it away from a second web or support—thereby causing the peelable seal to “fail.” The type of failure depends on the design and location of the peelable layer. With an “interfacial peel” or “surface peel,” the peelable layer may be located as an outer sealant layer of the top film, so that the top film separates from the substrate to which it adheres at the interface between the peelable layer of the top film and the substrate. Alternatively, with a “delamination peel,” the peelable layer may be located as an internal layer of the top film, so that the top film separates between the peelable layer and another layer of the top film (i.e., interlayer separation).
The peelable seal failure mechanism may be further classified as: 1) a “cohesive failure,” in which the molecular attractive forces holding together the peelable layer composition are overcome, or 2) an “adhesive failure,” in which the interfacial forces (e.g., valence forces or interlocking action or both) holding two surfaces together are overcome, or 3) a combination of both. Regardless of the type of peelable seal failure, it is desirable that the failure not cause “angel hair” or strings of resin to form or remain between the peeled layer and the substrate upon peeling.
The peelable seal should be sufficiently strong to withstand the expected abuse during the packaging operation, distribution, and storage. If the seal bond strength is too weak, then the package may open prematurely. However, the peelable seal must also provide a sufficiently low bond strength to allow the end-user to easily peel open the package by hand. If too high of a peel force is needed to open the peelably sealed packaging, then the peelable film may be considered “locked down”—that is, too hard to open easily by hand.
If the peelable layer of the film is an outer, sealant layer of the film, then it is desirable that the peelable layer have a relatively low heat seal initiation temperature in order to allow the equipment used to form the heat seals to run at relatively fast speeds. Further, it is also desirable that a packager be able to increase the bond strength of the peelable seal merely by increasing the heat seal temperature at which the peelable seal is made. This is because the packager may desire to form a less easily peeled seal for some applications (e.g., liquid packaging) than others (e.g., dry cereal packaging). However, it is also desirable that the peelable seal strength gradually increase as the sealing temperature increases, so that the sealing temperature does not have to be monitored so closely by the packager. Otherwise, a relatively small drift or variation in the sealing temperature that may be associated with the sealing equipment may cause a large variation in the peelable seal strength.
The bottom web or substrate of an easy-open package is often an ionomer-based surface or an LLDPE-based surface, depending on the packaging application and the desired performance attributes. However, existing peelable films that form an acceptable peelable seal at a given temperature with an ionomer-based surface generally do not tend to form an acceptable peelable seal at the same given temperature with an LLDPE-based surface. Conversely, peelable films that form an acceptable peelable seal at a given temperature with an LLDPE-based surface generally do not tend to form an acceptable peelable seal at the same given temperature with an ionomer-based surface. As a result, packagers that use both ionomer-surfaced substrates and LLDPE-surfaced substrates in providing easy-open packaging must currently purchase at least two separate types of top film or lid stock depending on the composition of the substrate. Further, to meet this demand, peelable film suppliers must be able to provide at least two types of compatible top film or lid stock to the packagers. This increases the amount of peelable film inventory that the easy-open packager or peelable film supplier must carry—and also increases the complexity and cost of the manufacture of easy-open packaging.
SUMMARY OF THE INVENTION
The present invention addresses one or more of the aforementioned problems. A peelably sealed package includes a web having a peelable layer and a substrate having a surface layer. The peelable layer includes a blend of: i) from about 3 to about 15 weight parts polybutylene, ii) from about 40 to about 75 weight parts ionomer, and iii) from about 20 to about 55 weight parts ethylene/unsaturated ester copolymer. The unsaturated ester may be a vinyl ester of aliphatic carboxylic acid, where the vinyl ester has from 4 to 12 carbon atoms, or an alkyl ester of acrylic or methacrylic acid, where the alkyl ester has from 4 to 12 carbon atoms. The surface layer of the substrate includes a polyethylene having a density of from about 0.915 to about 0.93 g/cc, an ionomer, or a mixture of these polymers. The peelable layer of the web and the surface layer of the substrate are peelably sealed to each other in one or more selected areas.
In another aspect, a thermoplastic film useful as a peelable film has at least one layer comprising a blend of from about 3 to about 15 parts polybutylene, from about 40 to about 75 parts ionomer, and from about 20 to about 55 weight parts ethylene/unsaturated ester copolymer. The unsaturated ester is a vinyl ester of aliphatic carboxylic acid, where the vinyl ester has from

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