Electricity: electrical systems and devices – Electrolytic systems or devices – Liquid electrolytic capacitor
Reexamination Certificate
2001-03-07
2003-01-21
Nguyen, Chau N. (Department: 2831)
Electricity: electrical systems and devices
Electrolytic systems or devices
Liquid electrolytic capacitor
C361S511000, C361S523000, C361S528000, C361S502000
Reexamination Certificate
active
06510044
ABSTRACT:
BACKGROUND OF THE INVENTION
The present invention relates to a paste for the production of sintered coatings of refractory metal powders, particularly for electrolytic capacitor electrodes made of tantalum, niobium or alloys thereof. The invention relates in particular to a process for the pressureless production of tantalum and/or niobium capacitor electrodes. The invention also relates in particular a process for the production of new types of electrodes and capacitors by means of pastes. The invention further relates to new types of capacitor electrodes comprising sheet-like supports.
Tantalum capacitors consist of a porous sintered layer of pre-agglomerated tantalum powder, which is coated with a layer of a dielectric insulator, namely an oxide layer, and which is deposited on a tantalum wire which serves firstly as an electrical contact and secondly as a support. The counterelectrode is formed by a liquid, paste-like or solid electrolyte. The high specific capacitance of capacitors of this type is due to the large surface area of dielectric which is provided by the porosity of the sintered layer. The sintered layer is produced by pressing and sintering the free-flowing powder. An analogous procedure is employed for the production of niobium capacitors.
It is first of all clear that the pressing procedure, comprising the insertion of the contact wire in the press mould, the introduction of the free-flowing powder into the gap between the contact wire and the press mould, the compaction of the powder, etc., is a costly procedure. Furthermore, this procedure only permits a limited range of shapes and dimensions to be fabricated.
On the other hand, paste deposition processes enable pressureless sintering to be effected, enable almost any shapes and dimensions to be produced corresponding to the capacitor design, and also enable thin, sheet-like anodes to be produced in particular.
One problem with the development of finer and finer acidic earth metal powders in order to achieve higher specific capacitances is the associated effect of the increasing current density in the sintered body in the surroundings of the supporting wire, which can result in overheating and in the spontaneous reaction of the MnO
2
counterelectrode with the sintered anode (burning away of the acidic earth metal powder). A sheet-like construction of the sintered body would result in a reduction in current density and would ensure better dissipation of heat.
Accordingly, a process which enables sintering to be effected after applying a paste to the contact wire or to a contact sheet would be associated with significant technical advantages at a considerably lower production costs. Despite the obvious advantages which a process such as this would offer, no proposals for a process such as this have hitherto become known or have been introduced into industry. The reason for this is that no pastes have hitherto become known which would satisfy the diverse and complex requirements of capacitor production. The problem to be solved consists of identifying a continuous phase for the paste, which at the same time does not affect the extremely sensitive surface of the tantalum or niobium powder, particularly before and during sintering, which can be removed from the sintered layer without leaving a residue, and which nevertheless provides the requisite rheological properties for the deposition of paste on the substrate, which imparts a satisfactory level of stability to the deposited paste-like layer, and which moreover can be removed from the tantalum powder layer without impairing the microstructure thereof.
Numerous investigations have shown that pastes comprising a continuous phase based on water or low-boiling organic solvents do not impart an adequate level of stability to the powder microstructure. At an elevated temperature, or even at room temperature, they dry with the formation of bubbles, and may even produce a foam. Inorganic or mineral rheology-modifying agents are ruled out due to contamination of the tantalum surface by inorganic residues. It is also necessary to avoid contamination by carbon which is formed from residues of organic constituents of the continuous phase.
It has now been found that pastes which result in a continuous phase which, optionally after the evaporation of a low-boiling solvent, substantially consists of organic substances which are synthesised from carbon, oxygen and hydrogen only, and in which the ratio of the number of oxygen atoms to carbon atoms is at least 0.5, preferably at least 2/3, more preferably at least 0.8 and most preferably 1, do not leave behind any troublesome carbon residues after sintering under high vacuum. Pastes of this type enable acidic earth metal capacitors to be produced in sheet form.
SUMMARY OF THE INVENTION
The present invention relates to anodes for electrolytic capacitors based on sintered acidic earth metal powders, consisting of a metallic support which is constructed as an electrical contact, and of a porous sintered body which constitutes the capacitor surface and which is attached to the support, wherein the supporting body is constructed in the form of a metal sheet.
The present invention also relates to electrolytic capacitors comprising a sintered acidic earth metal powder anode, which is of sheet-like construction, i.e. the geometric extent thereof in two dimensions is greater than the extent thereof in the third dimension.
The anodes according to the invention are preferably constructed so that the supporting metal sheet protrudes beyond the sintered body in at least one direction. This results in a further improvement in the dissipation of heat and in a simplification of the system of electrical contacts.
According to the invention, the supporting metal sheet, which preferably consists of Nb or Ta, can have a length to width ratio of 3:1 to 10:1 or more, wherein a partial surface area of 0.5 to 100 mm
2
, preferably 2 to 40 mm
2
, of the supporting metal sheet is provided on one or both sides with the sintered body.
The supporting metal sheet can have a thickness from 30 to 500 &mgr;m, preferably 40 to 300 &mgr;m, most preferably 60 to 150 &mgr;m. The sintered body which is sintered thereon can have a thickness from 20 to 2000 &mgr;m, preferably more than 100 &mgr;m, most preferably 300 to 1000 &mgr;m.
The present invention further relates to a process for the production of sintered refractory metal layers, consisting of 40 to 92% by weight of a refractory metal powder as a discrete phase, and of a continuous phase which substantially consists of organic compounds which are synthesised from carbon, oxygen and hydrogen only, wherein the ratio of the number of oxygen atoms to carbon atoms is at least 1/2, and optionally consisting of a solvent which evaporates below 100° C. The amount of refractory metal powder preferably ranges from 10 to 50% by volume of the paste.
Although the invention is described below using tantalum as an example, it can also be used correspondingly for niobium and other refractory metals such as molybdenum, tungsten and alloying metals.
Compounds which are liquid at room temperature are preferably used as the organic compounds. In this case, the remainder of the continuous phase is preferably free from solvent. Examples of suitable liquid organic compounds include ethylene glycol, diethylene glycol, tri- and tetraethylene glycol and esters thereof, glycerol, glycerol monoacetate, glycerol diacetate, glycerol triacetate, dioxyacetone, propanediol or mixtures thereof. Moreover, the continuous phase preferably contains an organic binder system in addition. The binder system preferably consists of two components which are capable of crosslinking with each other. The binder should be used in amounts of not more than 5% by weight with respect to the continuous phase. One preferred binder system consists of Natrosol® Plus 331 supplied by Hercules or of an acrylic polymer, for example Rohagit® KF720 supplied by Röhm. Wetting agents, such as soya lecithin supplied by Langer and/or Sulfinols as supplied by Biesterfeld
Binner Karsten
Gottschling Marianne
Löffelholz Josua
Eyl Diderico van
Gil Joseph C.
H. C. Starck GmbH & Co. KG
Ha Nguyen
Nguyen Chau N.
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