Passivation of thin film oxide superconductors

Superconductor technology: apparatus – material – process – High temperature – per se – Having tc greater than or equal to 150 k

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505701, 505702, 505703, 505704, 428 76, 428426, 428432, 4284735, 428688, 428930, B32B 900

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051149109

ABSTRACT:
An oxide superconductor having a high critical temperature is provided with a passivation coating comprising a first layer of a Group II oxide, such as magnesium oxide, and a second layer of a polymer, such as polyimide. The Group II oxide is formed under conditions to be substantially amorphous. After depositing the Group II layer, the encapsulated superconductor is heated to an elevated temperature for a period of time in an oxidizing atmosphere. This restores the high critical temperature to its original value. The polymer is then coated on top of the Group II oxide and cured. The passivation coating is resistant to strong acids, strong bases, and water, is robust, hard, and resilient against scratching.

REFERENCES:
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Formation of Crystallized Buffer Layer for High to Superconducting Thin Film, Shinohara et al., Oct. 1988.
High Temperature Superconductors, Gubner et al., Apr. 1987.
"Reactivity and Passivation for Bi Adatoms on YBa.sub.2 Cu.sub.3 O.sub.6.9 and Bi.sub.2 Ca.sub.1+x Sr.sub.2-x Cu.sub.2 O.sub.8+y ", H. M. Meyer et al., Appl. Phys. Lett. 53(11), 12 Sep. 1988, pp. 1004-1006.
"SiO.sub.2 and Si.sub.3 N.sub.4 passivation layers on Y-Ba-Cu-O Thin Films", Q. X. Jia et al., J. Appl. Phys. 66(1), 1 Jul. 1989, pp. 452-454.
"Surface and Interface Properties of High-Temperature Superconductors", H. Meyer, III et al., Chemistry of High-Temperature Superconductors, pp. 280-290.

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