Passivating metals on cracking catalysts

Catalyst – solid sorbent – or support therefor: product or process – Zeolite or clay – including gallium analogs – Including organic component

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502 64, 502100, 502521, B01J 2906, B01J 2314, B01J 3300

Patent

active

045350663

ABSTRACT:
A cracking catalyst used to crack oil to produce gasoline or higher-boiling hydrocarbon fuel is contacted with both (A) antimony or a compound thereof such as antimony tris(0,0-dipropyl phosphorodithioate) and (B) a modifying composition consisting essentially of carbon, hydrogen, nitrogen, and sulfur produced by the treatment of a metal salt of a dialkyl dithiocarbamate with a hydrolyzable germanium (IV) compound such as germanium tetrachloride, the contacting of the catalyst with (A) and (B) prior to, during, or after use of the catalyst in a cracking process being effective in precluding or reducing adverse effects of metals such as nickel, vanadium, and iron.

REFERENCES:
patent: 4255287 (1981-03-01), Bertus et al.
patent: 4326990 (1982-04-01), Mark et al.
patent: 4397767 (1983-08-01), Roberts et al.

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