Passivating metals on cracking catalysts

Catalyst – solid sorbent – or support therefor: product or process – Regenerating or rehabilitating catalyst or sorbent – Treating with a liquid or treating in a liquid phase,...

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208 52CT, 208113, 208120, 502 31, 502 38, 502 60, 502 63, 502232, 502263, B01J 2938, B01J 2926, B01J 2120, C10G 1105

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044593660

ABSTRACT:
A cracking catalyst used to crack oil to produce gasoline or higher-boiling hydrocarbon fuel is contacted with both (A) antimony or a compound thereof such as antimony tris(O,O-dipropyl phosphorodithioate) and (B) a modifying composition consisting essentially of carbon, hydrogen, nitrogen, and sulfur produced by the treatment of a metal salt of a dialkyl dithiocarbamate with a hydrolyzable germanium (IV) compound such as germanium tetrachloride, the contacting of the ctalyst with (A) and (B) prior to, during, or after use of the catalyst in a cracking process being effective in precluding or reducing adverse effects of metals such as nickel, vanadium, and iron.

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patent: 4334979 (1982-06-01), Bertus et al.

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