Compositions – Preservative agents – Anti-oxidants or chemical change inhibitants
Patent
1979-06-11
1981-02-17
Gantz, Delbert F.
Compositions
Preservative agents
Anti-oxidants or chemical change inhibitants
252428, 252429R, B01J 2714, B01J 3102
Patent
active
042513901
ABSTRACT:
An improvement in the oxidation catalyst used for the partial oxidation of n-butane and containing vanadium and phosphorus mixed oxides which comprises adding a zinc compound in an amount of from about 0.15 to 0.001/l Zn/V to the catalyst during the digestion of the reduced vanadium component by concentrated phosphoric acid. The addition of zinc produces a catalyst which is more easily activated and which is very stable to heat upset of the reaction system. Small amounts of lithium and silicon compounds also have additional desirable catalytic effects without dimunition of the zinc compound benefit.
REFERENCES:
patent: 3156706 (1964-11-01), Kerr
patent: 3255211 (1966-06-01), Kerr
patent: 3985775 (1976-10-01), Harrison
patent: 4016105 (1977-04-01), Kerr
patent: 4017521 (1977-04-01), Schneider
patent: 4043943 (1977-08-01), Schneider
patent: 4062873 (1977-12-01), Harrison
patent: 4151116 (1979-04-01), McDermott
Denka Chemical Corporation
Gantz Delbert F.
Johnson Kenneth H.
Wright William G.
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