Paraffin treating process for mercaptan and olefin removal

Organic compounds -- part of the class 532-570 series – Organic compounds – Sulfur containing

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568697, 208189, 208192, C07C31916

Patent

active

054631343

ABSTRACT:
Contaminants such as mercaptans, oxygenates and olefins are removed from paraffin-rich feed streams through the use of catalytic distillation performed using an acid catalyst such as a sulphonated resin in the substantial absence of hydrogen. The mercaptans are reacted with the olefins to form less volatile thioethers removed as part of a net bottoms stream with the treated paraffins being removed as the overhead stream.

REFERENCES:
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patent: 4775462 (1988-10-01), Imai et al.
patent: 5254748 (1993-10-01), Hensley et al.
patent: 5304683 (1994-04-01), Sattich
patent: 5321163 (1994-06-01), Hickey et al.
K. L. Rock. "Reduce the Cost of Producing TAME", Presented at the 1994 National Petroleum Refiners Association Annual Meeting, Mar. 20-22, 1994, pp. 1-6.

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