Para-selective aromatization process with ex situ selectivated z

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By ring formation from nonring moiety – e.g. – aromatization,...

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585400, 585467, 585475, 585481, C07C 1500

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active

055741991

ABSTRACT:
A process for shape selective hydrocarbon aromatization that involves contacting a hydrocarbon feedstream, under aromatization conditions, with a catalytic molecular sieve which has been modified by being ex situ selectivated with a silicon compound. The ex situ selectivation involves exposing the catalytic molecular sieve to at least two selectivation sequences, each sequence comprising contacting the catalytic molecular sieve with a silicon compound followed by calcination. Optionally, the modified catalytic molecular sieve may be further selectivated in situ.

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