Palladium-nitrile ligand catalyst system and oxidation process

Details Palladium-nitrile ligand catalyst system and oxidation process Palladium-nitrile ligand catalyst system and oxidation process

1987-08-21

1988-04-19

Garvin, Sr., Patrick P.

Catalyst, solid sorbent, or support therefor: product or process

Catalyst or precursor therefor

Organic compound containing

568401, B01J 3128, B01J 3130

Patent

active

047389435

ABSTRACT:
A substantially chloride-free palladium oxidation system, comprising a palladium component, a copper component, and a ligand is described. The Wacker system, consisting of palladium and copper chlorides is also improved by the addition of a ligand. The palladium and copper counterion are independently selected from BF.sub.4.sup.-, CF.sub.3 COO.sup.-, SO.sub.4.sup.=, and NO.sub.3.sup.-. The ligand is preferably a nitrile-containing compound.

REFERENCES:
patent: 3849336 (1974-11-01), Lloyd et al.
patent: 4155879 (1979-05-01), Mimoun et al.

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