Palladium-containing fixed-bed catalyst for the hydrogenation of

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Metal – metal oxide or metal hydroxide

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502326, 502328, 502329, 502339, B01J 2300

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active

055211399

ABSTRACT:
Catalyst and process for the preparation of butene-2-diol-1,4 by the hydrogenation of butyne-2-diol-1,4 in aqueous solution over a palladium-containing fixed-bed catalyst, which is doped with lead or cadmium, in which a catalyst is used which has been made by applying Pd and Pb or Pd and Cd successively, by vapor deposition or sputtering, to a metal gauze or a metal foil acting as support material followed by forming the catalyst at an elevated temperature in air.

REFERENCES:
patent: 2681938 (1950-06-01), Lindlar
patent: 4001344 (1977-01-01), Hoffmann et al.
patent: 4438285 (1984-03-01), Codignola
patent: 4686202 (1987-08-01), Broecker
patent: 4795733 (1989-01-01), Thomas
patent: 5063194 (1991-11-01), Broecker et al.

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