Palladium catalyzed carboalkoxylation of butadiene

Details Palladium catalyzed carboalkoxylation of butadiene Palladium catalyzed carboalkoxylation of butadiene

1990-03-29

1991-06-25

Killos, Paul J.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

C07C 6736

Patent

active

050269011

ABSTRACT:
A process for the preparation of linear alkyl pentenoates by reacting butadiene, carbon monoxide and an alkyl alcohol in an organic solvent with a homogeneous catalytic mixture containing five components namely, palladium, chloride, a strong acid, an aryl monodentate phosphine, and a N-heterocyclic base.

REFERENCES:
patent: 4172087 (1979-10-01), Knifton
patent: 4824817 (1989-04-01), Drent

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