Cleaning compositions for solid surfaces – auxiliary compositions – Cleaning compositions or processes of preparing – For cleaning a specific substrate or removing a specific...
Reexamination Certificate
1999-07-19
2001-03-13
Gupta, Yogendra (Department: 1751)
Cleaning compositions for solid surfaces, auxiliary compositions
Cleaning compositions or processes of preparing
For cleaning a specific substrate or removing a specific...
C510S201000, C510S202000, C510S203000, C510S488000, C510S505000, C034S080000
Reexamination Certificate
active
06200940
ABSTRACT:
FIELD OF THE INVENTION
This invention relates to paint stripper compositions containing malic acid and methods of preparing the same.
BACKGROUND OF THE INVENTION
For decades, strong acids and halocarbon solvent-based compositions were employed in stripping various protective coatings from metal and other substrates. Increased awareness of the detrimental impact of such paint strippers on health and environment, in recent years, resulted in government legislative bodies all over the world restricting and/or prohibiting the use of these materials. Furthermore, these paint strippers often damaged the substrates to which they were applied.
Wilkins et al., U.S. Pat. No.5,215,675 provides an aqueous stripping composition based on a soluble ester such as ethyl lactate and a peroxide such as hydrogen peroxide.
Distaso, U.S. Pat. No. 5,405,548 and U.S. Pat. No. 5,542,986 describe the use of methylbenzyl formate or benzyl formate and formic acid in an aqueous-based system for stripping various protective coatings.
However, these prior art compositions suffer from several disadvantages, namely, low solvency (low efficacy), high cost, corrosiveness, narrow range of stability, and extremely strong, unpleasant, and irritating odor.
SUMMARY OF THE INVENTION
The present invention is directed to a paint stripper composition comprising (a) from about 5 to about 50% by weight of aromatic alcohol; (b) from about 0.5 to about 20% by weight of malic acid; and (c) from about 15 to about 60% by weight of water. The pH of the composition broadly ranges from about 2 to about 3. The paint stripper composition of the present invention is free of chlorinated solvents, environmentally safe and user-friendly. It is also non-corrosive or only slightly corrosive to substrates, non-flammable, non-toxic, low odor, and fully biodegradable.
Another embodiment of the invention is a method of preparing the composition comprising dispersing (i) a polar phase containing (a) from about 0.5 to about 20 parts by weight of malic acid and (b) from about 15 to about 60 parts by weight of deionized or distilled water into (ii) a non-polar phase containing from about 5 to about 50 parts by weight of aromatic alcohol.
Yet another embodiment of the invention is a method for removing paint or a coating from a substrate comprising applying a paint or coating removing effective amount of the paint stripper composition of the present invention.
DETAILED DESCRIPTION OF THE INVENTION
The paint stripper composition of the present invention comprises (a) from about 5 to about 50% by weight of (i) an aromatic alcohol having the formula
where X, Y, and Z are all hydrogen or two hydrogens and a methyl, (ii) an aromatic alcohol having the formula
where R is ethylene, propylene, or isopropylene, or (iii) a mixture thereof; (b) from about 0.5 to about 20% by weight of malic acid; and (c) from about 15 to about 60% by weight of water based upon 100% weight of total composition. The composition preferably comprises (a) from about 25 to about 35% by weight of aromatic alcohol; (b) from about 0.5 to about 5% by weight of malic acid; and (c) from about 20 to about 50% by weight of water. More preferably, the composition comprises from about 0.5 to about 3% by weight of malic acid.
The composition typically has a pH of from about 2 to about 3.
Suitable aromatic alcohols include, but are not limited to, benzyl alcohol, phenoxy propanol, phenoxy ethanol, and any combination of any of the foregoing. Preferably, the aromatic alcohol is benzyl alcohol.
The malic acid of the composition initiates removal of paint or a coating on a substrate. In particular, compositions of the present invention have been found to be very effective at removing antifouling paint from various substrates, including, but not limited to, polyester and metallic substrates. Malic acid is also non-corrosive to metallic substrates.
Additionally, malic acid is a good fluxing agent. Hence, the paint stripper composition of the present invention spreads very well on solid surfaces, which improves the efficacy of stripping by reducing the waiting time for the paint to start lifting.
The presence of deionized water in the composition enhances the overall stripping effectiveness of the composition. When the protective coating on a substrate to which the composition is applied is polar, e.g., polyurethanes, the presence of a solvent with a high dielectric constant such as water (&egr;=80.2@20° C.) has a positive effect in separating charged areas, thus allowing other solvents in the composition to soften the coating.
The water preferably contains no more than about 1% by weight of dissolved inorganic salts and preferably less than about 200 ppm. Distilled or deionized water having an electrical conductivity less than about 400 mho/cm is particularly preferred. Failure to follow the above specified water parameters may result in decomposition of peroxides in the composition, which may retard the stripping performance of the composition.
The composition may also include an aromatic ether having the formula R
1
—CH
2
—O—CH
2
—R
2
where R
1
and R
2
are hydrogen and phenyl or both phenyl. A preferred aromatic ether is benzyl ether. The composition preferably includes from about 1 to about 30% by weight of aromatic ether based upon 100% weight of total composition. The weight ratio of aromatic alcohol to aromatic ether is preferably from about 3:1 to about 1:1 and more preferably about 2.5:1.
An aromatic hydrocarbon cosolvent may be included in the composition. The aromatic hydrocarbon cosolvent may be a mixture of one or more aromatic hydrocarbon solvents. The aromatic hydrocarbon cosolvent improves the stability of the composition thereby increasing the shelf life of the composition. It also improves the rheological properties of the composition and the speed of penetration of the composition into paints and coatings. Furthermore, the aromatic hydrocarbon solvent reduces the surface tension and evaporation rate ofthe composition. Preferably, the aromatic hydrocarbon solvent has a flash point above about 150° F. and more preferably above about 190° F. Naphthalene depleted aromatic hydrocarbons are preferable since naphthalene has a noxious odor and is hazardous. Suitable aromatic hydrocarbon cosolvents, include, but are not limited to, Aromatic 200ND available from Exxon Chemicals of Houston, Tex.; Solvesso 200 available from Esso Corporation of Toronto, Canada; metaphenoxy benzyl alcohol; and any combination of any of the foregoing. The composition typically comprises from about 0.5 to about 40% by weight and more preferably from about 1 to about 30% by weight of aromatic hydrocarbon cosolvent based upon 100% weight of total composition. The weight ratio of water to aromatic hydrocarbon cosolvent is typically from about 30:1 to about 1.5:1 and preferably from about 20:1 to about 1.7:1.
The composition may include a second hydroxycarboxylic acid having the empirical formula C
n
H
m
(COOH)
x
OH
y
where n, x, and y are independently integers greater than 1 and m is equal to 2n+2−(x+y). A preferred hydroxycarboxylic acid is glycolic acid. The inventor has discovered that the combination of malic acid and glycolic acid in a paint stripper composition of the present invention greatly enhances removal of antifouling paint from a substrate. Preferably the composition contains from about 0.5 to about 10% by weight and more preferably from about 0.5 to about 3.5% by weight of the second hydroxycarboxylic acid based upon 100% weight of total composition.
A peroxide generating agent may also be included in the composition. Preferably, the peroxide generating agent is hydrogen peroxide, magnesium peroxide, or any combination of any of the foregoing. On most metal surfaces, including aluminum and its alloys, a decomposition reaction of hydrogen peroxide takes place, generating an intermediate nascent oxygen which associates instantaneously, producing gaseous oxygen and water. The oxygen accelerates the stripping process by initiating the lifting of the softened protec
Darby & Darby
Gupta Yogendra
Napier International Technologies Inc.
Webb Gregory E
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