Adhesive bonding and miscellaneous chemical manufacture – Methods – Surface bonding and/or assembly therefor
Reexamination Certificate
1997-04-03
2002-10-22
Gallagher, John J. (Department: 1733)
Adhesive bonding and miscellaneous chemical manufacture
Methods
Surface bonding and/or assembly therefor
C156S308800, C156S324000, C156S327000, C156S333000, C428S308800, C524S556000, C524S567000, C524S568000
Reexamination Certificate
active
06468382
ABSTRACT:
BACKGROUND OF THE INVENTION
A. Field of the Invention
The present invention concerns a packaging material with good gas barrier properties, also in addition a method of producing the material.
Foodstuffs and other types of, oxidation and storage sensitive products already spoil or deteriorate after a very short time if they are exposed to the action of oxygen. In order to be able to package and keep the product for at least a certain time with maintained fresh qualities it is thus required that the product should be packaged in a packaging which is difficult to penetrate or best of all completely impenetrable for oxygen which would otherwise easily be able to penetrate into the packaging and cause the product to,deteriorate.
B. Description of Relevant Art
A well known example of a packaging material which has good gas barrier properties and which is often used in packagings for liquid foodstuffs of the type, such as juice, wine, edible oil etc is built up of layers of paper or cardboard and plastic with a gas barrier layer of aluminum (Al foil) applied to one side of the paper or cardboard layer. An Al foil is in itself completely impenetrable for oxygen and has also other valuable barrier properties for the product packaged. e.g. to penetrability by light, at the same time as during the forming of the material into packagings it makes it possible to execute tight and mechanically strong joints in the material through inductive heating. The problem with Al foil has, however, always been that it is expensive and that it is practically inelastic which has often entailed that it has cracked or burst in regions of material which have been exposed to particularly strong tensile strains during production of the packaging. There has therefore been a wish to find a cheaper but just as effective alternative to Al foil.
The Swedish patent no. 8200761-8 gives details of a packaging material completely free from Al foil with good barrier properties. This known material comprises a skeletal layer of paper or cardboard and a gas barrier layer of polyvinyl alcohol (PVAL) applied to one side of the skeletal layer. A layer of PVAL has, as is known, good gas-tight properties so long as the polymer layer is dry, but quickly loses its barrier properties in proportion as the moisture content in the layer increases. In order to protect the PVAL layer against moisture it is therefore proposed in the Swedish patent that the outside of the PVAL layer should be covered with plastic, preferably polyethylene. According to the Swedish patent the packaging material is produced through an aqueous dispersion or aqueous emulsion of PVAL being applied along one side of a strip or a sheet of paper or cardboard, after which “the surplus water” in the layer applied is driven away through heating to form a dry, coherent PVAL layer. The PVAL layer and the other side of the strip or sheet are subsequently coated with the moisture-repellent plastic coatings which are extruded on to the two sides of the strip or sheet.
The disadvantage with the procedure described in the Swedish patent is that PVAL cannot be applied as a pure aqueous dispersion or aqueous emulsion but requires at least one further chemical component or thickener in order to avoid the water in the dispersion or emulsion applied being sucked into and absorbed by the water-absorbent material in the strip or sheet. Another disadvantage which is at least partly connected with the water-absorbent properties of the sheet or strip material is that the PVAL layer applied must be dried through heating in order to adjust the correct moisture content in the PVAL layer, which makes the known procedure energy and therefore cost intensive.
SUMMARY OF THE INVENTION
An aim of the present invention is to give details about a packaging material with good gas barrier properties without problems or disadvantages of the kind described above.
This aim is achieved according to the invention through the fact that a packaging material of the type described in the introduction is given the characteristics that it comprises a first and second layer of a fibrous material and a layer of a water based polymer between and in direct contact with the layers of fibrous material, which functions both as a binding agent and as a gas barrier in the packaging material.
Another aim of the invention is to indicate a method of producing the laminated packaging material with the use of a water based polymer of, for example, the type which is described in the abovementioned patent, without any requirements either for further chemical components or for thickeners and without any requirements to dry an applied polymer layer through energy and cost intensive heating.
This aim is achieved according to the invention through the fact that the method is given the characteristics that a first and a second strip or a first and a second sheet of a fibrous material are brought together and bound to each other with the aid of a layer of a water based polymer which is added between and in direct contact with the strips or sheets, and that the fibrous, material in one or both strips or in one or both sheets is, utilized to absorb away water from and adjust the moisture content in the water based polymer to form an intermediate layer functioning as binding agent and gas barrier in the packaging material.
Further advantageous and practical embodiments of the packaging material and method of producing the packaging material according to the invention respectively have further been given the characteristics mentioned in the sub-claims below.
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patent: 3112235 (1963-11-01), Blanchard
patent: 3249482 (1966-05-01), Gilfillan
patent: 3313757 (1967-04-01), Trofimow et al.
patent: 3347811 (1967-10-01), Bissot
patent: 3684643 (1972-08-01), Stepp
patent: 3778399 (1973-12-01), Fazioli et al.
patent: 3886017 (1975-05-01), Brugh et al.
patent: 4701360 (1987-10-01), Gibbons et al.
patent: 4789575 (1988-12-01), Gibbons et al.
patent: 0 181 579 (1986-05-01), None
patent: 52-001115 (1977-01-01), None
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Hawley, Condensed Chemical Dictionary, 9th Edition, © 1977, p. 857.
Andersson Thorbjörn
Asp Ann-Magret
Burns Doane Swecker & Mathis L.L.P.
Gallagher John J.
Tetra Laval Holdings & Finance S.A.
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