P-carboxyphenyl-azoxycarbonitrile and its methyl ester

Details P-carboxyphenyl-azoxycarbonitrile and its methyl ester P-carboxyphenyl-azoxycarbonitrile and its methyl ester

1974-09-05

1977-02-22

Curtis, Allen B.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

195 29, 195 51R, 260143, C07C10500

Patent

active

040091554

ABSTRACT:
There is disclosed a new antibiotic called calvatic acid having the structure p-carboxyphenyl-azoxycarbonitrile and processes for its production by fermentation and processes for its recovery and purification. This substance is effective in inhibiting the growth of Gram-positive bacteria and carcinoma.

REFERENCES:
patent: 2119891 (1938-06-01), Seidenfaden et al.
patent: 3597414 (1971-08-01), Gruffaz et al.
patent: 3819609 (1974-06-01), Puklics et al.
Alfieri et al., Chem. Abs. vol. 75, 1971, 109084e.
Rodionow et al., Bull. Soc. Chem. [5], vol. 4, p. 1703, (1937).
Freeman, The Nuclear Magnetic Resonance Spectra & Structure of Aliphatic Azoxy Compounds, vol. 28, pp. 2508-2511 in Structure of Aliphatic Azoxy Compounds, Oct., 1943.
"A New Antibiotic, Calvatic Acid", J. Antibiotics, 28 (1) 87-90 (1975).
Gasco et al., "An Antibacterial and Antifungal Comp'd from Calvatia Lilacina", Tetrahedron Ltrs., 3431-3432 (1974).

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