Oxyiodination process for manufacture of 2,6-diiodonaphthalene

Organic compounds -- part of the class 532-570 series – Organic compounds – Halogen containing

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C07C 17152

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active

050829823

ABSTRACT:
Disclosed is a process for preparation of a stream which is both selectively high in 2,6-diiodonaphthalene and also contains substantial quantities of diiodonaphthalene. First, naphthalene is oxyiodinated in the presence of a zeolite catalyst to produce a stream which is selectively high in 2-monoiodonaphthalene and the 2-monoiodonaphthalene is separated from the stream to produce a stream which is both selectively high in 2-monoiodonaphthalene and contains substantial quantities of 2-monoiodonaphthalene. Second, this stream is then oxyiodinated in the presence of a zeolite catalyst to produce a stream which is selectively high in 2,6-diiodonaphthalene and then 2,6-diiodonaphthalene is separated from the stream to produce the stream which is both selectively high in 2,6-diiodonaphthalene and contains substantial quantities of 2,6-diiodonaphthalene.

REFERENCES:
patent: 4746758 (1988-05-01), Rule et al.
patent: 4788356 (1988-11-01), Tustin

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