Compositions – Reductive bleachant – deoxidant – reductant – or generative – Deoxidant or oxygen scavenging
Reexamination Certificate
1999-06-16
2001-04-10
Anthony, Joseph D. (Department: 1714)
Compositions
Reductive bleachant, deoxidant, reductant, or generative
Deoxidant or oxygen scavenging
C252S399000, C522S066000, C428S035800, C428S035200, C428S411100
Reexamination Certificate
active
06214254
ABSTRACT:
BACKGROUND INFORMATION
1. Field of the Invention
This invention relates to a composition useful in scavenging oxygen from environments containing oxygen-sensitive products, particularly food and beverage products. More specifically, the oxygen scavenging composition includes a polymer having mer units derived from a vinyl aralkyl compound, a transition metal compound and, optionally, a photoinitiator.
2. Background of the Invention
Limiting the exposure of oxygen-sensitive products to oxygen maintains and enhances the quality and shelf life of many products. For instance, by limiting the oxygen exposure of oxygen-sensitive food products in a packaging system, the quality of the food product can be maintained and spoilage retarded. In addition, such packaging also keeps the product in inventory longer, thereby reducing costs incurred from waste and having to restock.
In the food packaging industry, several techniques for limiting oxygen exposure have been developed. Common techniques include those where oxygen is consumed within the packaging environment by some means other than the packaged article or the packaging material (e.g., through the use of oxygen scavenging sachets), those where reduced oxygen environments are created in the package (e.g., modified atmosphere packaging (MAP) and vacuum packaging), and those where oxygen is prevented from entering the packaging environment (e.g., barrier films).
Sachets containing an oxygen scavenging compositions can contain ferrous compositions, which oxidize to their ferric state, unsaturated fatty acid salts on an absorbent, and/or a metal/polyamide complex. See, e.g., U.S. Pat. Nos. 4,908,151 and 5,194,478. The disadvantages of sachets include the need for additional packaging steps (to add the sachet to the package), the potential for contamination of the packaged article should the sachet break, and the danger of digestion by a consumer.
Oxygen scavenging materials also have been incorporated directly into the packaging structure. This technique (hereinafter referred to as “active oxygen barrier”) can provide a uniform scavenging effect throughout the package and can provide a means of intercepting and scavenging oxygen as it passes through the walls of a package, thereby maintaining the lowest possible oxygen level through-out the package. Active oxygen barriers have been formed by incorporating inorganic powders and/or salts as part of the package. See, e.g., U.S. Pat. Nos. 5,153,038, 5,116,660, 5,143,769, and 5,089,323. However, incorporation of such powders and/or salts can degrade the transparency and mechanical properties (e.g., tear strength) of the packaging material and can complicate processing, especially where thin films are desired. Also, these compounds as well as their oxidation products can be absorbed by food in the container, which can result in the food product failing to meet governmental standards for human consumption.
EP 0 519 616 discloses an oxygen scavenging composition that includes a blend of an epoxide, a first polymeric component grafted with an unsaturated carboxylic anhydride and/or acid, a second polymeric component including OH, SH, or NHR
2
groups where R
2
is H, C
1
-C
3
alkyl, or substituted C
1
-C
3
alkyl moiety, and a metal salt capable of catalyzing the reaction between oxygen and the second polymeric component. The first polymeric component is present in an amount sufficient to ensure that the blend is non-phase separated. A blend of polymers is utilized to obtain oxygen scavenging, and the second polymeric component is preferably a (co)polyamide such as MXD6.
Another type of active oxygen barrier is illustrated in EP-A-0 301 719, EP-A-0 380 319, PCT publication no. WO 90/00578, and PCT publication no. WO 90/00504. See also U.S. Pat. Nos. 5,021,515, 5,194,478, and 5,159,005. The disclosed oxygen scavenger includes polyamide-transition metal catalyst compositions. Through catalyzed scavenging by the polyamide, the package wall regulates the amount of oxygen reaching the interior of the package. However, the onset of useful oxygen scavenging (i.e., up to about 5.8×10
−5
cm
3
/m
2
·s or 5 cm
3
/m
2
·24 hours at ambient conditions) can take as long as 30 days to occur. Therefore, this technique is not acceptable for many applications. Further, polyamides typically are incompatible with many thermoplastic polymers commonly used to make flexible packaging materials (e.g., ethylene/vinyl acetate copolymers, low density polyethylene, etc.) or, when used by themselves, are difficult to process and result in inappropriately stiff structures.
Oxygen scavenging compositions that include transition metal catalysts and ethylenically unsaturated hydrocarbon polymers which have an ethylenic double bond content of from 0.01 to 10 equivalents per 100 grams of polymer are disclosed in U.S. Pat. No. 5,399,289. Various conventional homopolymers, copolymers, and polymer blends are disclosed. Because these polymers are amorphous, they can be difficult to blend and process with film-forming semi-crystalline polymers conventionally used to make flexible packaging materials.
The use of a transition metal and a photoinitiator to facilitate initiation of effective scavenging activity of ethylenically unsaturated compounds is taught in U.S. Pat. No. 5,211,875. Because of the limited compatibility of the scavenger polymer with the film forming polymer, the amount of scavenger polymer in the blend must be limited and the resultant composition is difficult to process.
PCT publication Nos. WO 95/02616 and WO 96/40799 disclose a scavenger composition that includes a transition metal salt and a copolymer (of ethylene and a vinyl monomer) having ether, amino, carboxylic acid, ester, or amide functionalities pendent therefrom. Although this composition can provide oxygen scavenging activity, the active components can act too slowly to be effective, do not have good hydrolytic stability, and can decompose during scavenging to impart odor, color, or taste impurities to the packaged product.
Ideally, a polymeric material for use in an oxygen scavenging composition should exhibit good processing characteristics, be able to be formed directly into useful packaging materials or have high compatibility with those polymers commonly used to make packaging materials, and not produce byproducts which detract from the color, taste, or odor of the packaged product. Optimally, a packaging material formed from such a composition can retain its physical properties after significant oxygen scavenging.
SUMMARY OF THE INVENTION
Briefly, the present invention provides an oxygen scavenging composition including a polymer that includes mer units derived from at least one vinyl aralkyl compound; a transition metal catalyst; preferably, a photoinitiator; and optionally, a diluent material. This composition has been found to exhibit a high degree of processability, to be highly compatible with conventional polymers used in forming packaging materials, to exhibit significant ability to scavenge oxygen while part of a film or article used to package an oxygen sensitive product, and to produce insignificant amounts of organoleptic byproducts which can detract from the packaged product's odor, color, and/or taste.
In other aspects, the present invention provides an article which include at least one layer formed from a blend that includes the foregoing composition as well as a method of scavenging oxygen in which a packaging article, at least one layer of which is formed from a blend that includes the foregoing composition, is exposed to actinic or e-beam radiation so as to activate the composition.
The following definitions apply herein throughout unless a contrary intention is expressly indicated:
“polymer” means the polymerization product of one or more monomers and includes homopolymers, as well as interpolymers;
“interpolymer” means the polymerization product of two or more kinds of monomers;
“(meth)acrylate” means acrylate or methacrylate;
“photoinitiator” means a substance which, when activated by actinic radiation, enhanc
Gauthier William
Speer Drew Ve.
Anthony Joseph D.
Cryovac Inc.
Quatt Mark B.
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