Oxygen-ruthenium oxide oxidation of 2-hydroxy-3,3-dimethyl-butan

Details Oxygen-ruthenium oxide oxidation of 2-hydroxy-3,3-dimethyl-butan Oxygen-ruthenium oxide oxidation of 2-hydroxy-3,3-dimethyl-butan

1986-05-23

1992-02-25

Garner, Vivian

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acids and salts thereof

562525, C07C 51373, C07C 59185

Patent

active

050915681

ABSTRACT:
In the oxidation of 2-hydroxy-3,3-dimethyl-butanoic acid in solution in the presence of a ruthenium oxide catalyst to produce 2-oxo-3,3-dimethyl-butanoic acid, the improvement wherein oxidation is effected with oxygen.

REFERENCES:
patent: 3479403 (1969-11-01), MacLean
patent: 4247716 (1981-01-01), Kiyoura
Ryland, Organic Synthesis with Noble Metal Catalysts, vol. 28 (1973), pp. 133-134.
Cotton et al., "Advanced Inorganic Chemistry" (third edition) Wiley, p. 846.
Silverman, Oak Ridge National Laboratory Report 746, Series A, Nov. 13, 1950, pp. 1, 2 and 7.
Trifiro, Chim. Ind., vol. 56, 1974.

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