Oxo-hexameric zirconium-octaamino acid antiperspirant salts

Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing

Reexamination Certificate

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C424S065000, C424S066000

Reexamination Certificate

active

07897799

ABSTRACT:
A process for preparing oxo-hexameric zirconium-octaamino acid, such as glycine, salt comprising: mixing zirconium (Zr):amino acid:and mineral acid, in a molar ratio of 1:about 1 to about 15:about 1.5 to about 3 to form a mixture; optionally, filtering the mixture; and optionally, drying the mixture. An oxo-hexameric zirconium-octaamino acid salt of the molecular formula: oxo-[Zr6AminoAcid8].Xy.nH2O, wherein Zr is zirconium, X is an anion of a mineral acid, and n and y are numerical values from 0 to 20. A method of making an antiperspirant active zirconium-aluminum-amino acid compound comprising mixing an oxo-hexameric zirconium-octaamino acid salt with aluminum chlorohydrex and/or aluminum chloride, and drying the mixture. The smallest oxo-hexameric zirconium-octaamino acid salt of this invention provides stability, efficacy, and shelf life of zirconium-amino acid species for formulations in antiperspirant and/or deodorant compositions.

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Pan, Long et al., Synthesis and Structural Determination of a Hexanuclear Zirconium Glycine Compound Formed in Aqueous Solution, Inorganic Chemistry, vol. 47, No. 13, pp. 5537-5539, May 31, 2008.
International Search Report from PCT/US2008/076105, Dec. 19, 2008.

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