Oxirane production

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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C07D30110

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active

056987196

ABSTRACT:
Oxirane compounds are formed by vapor phase catalytic molecular oxygen oxidation of a C.sub.3 -C.sub.10 olefin using a silver catalyst, and the selectivity to the oxirane product is enhanced by preconditioning the catalyst by contact with the olefin at elevated temperature in the absence of oxygen; oxygen is periodically pulsed to the reaction.

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Doctoral Thesis of Nicholas C. Rigas "Activation of Metal for Ethylene Epoxidation Transient Response Studies on Multicrystalline Powders", Washington University, Sever Institue of Technology, Dec., 1991.
Rigas, N.C. et al. "Transcient Response Studies on the Activation of Silver Metal Surfaces for Ethylene Epoxidation", American Chemical Society, Washington, DC, Aug. 1992.
Park et al. "Ethylene Epoxidation on a Silver Catalyst: Unstead and Steady States Kinetics", J. Catalysis, 105, pp.81-94, 1987.

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