Oxide superconductor and process for producing the same

Superconductor technology: apparatus – material – process – High temperature – per se – Having tc greater than or equal to 150 k

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505785, 505729, 428930, 501123, 501152, 501153, 501154, 501108, 501127, 501126, 501102, 252521, H01L 3900

Patent

active

052848221

ABSTRACT:
Disclosed are an oxide superconductor, and an optimum process for producing the same. The oxide superconductor comprises a base material phase including an oxide superconducting material, the oxide superconducting material including barium (Ba) at least and being free from grain boundaries, and precipitation phases contained in an amount of 1 to 50% by volume in the base material phase and dotted therein in a manner like islands, the precipitation phases being oxides of a metal selected from the group consisting of silicon (Si), aluminum (Al), zirconium (Zr), magnesium (Mg), titanium (Ti), strontium (Sr), tungsten (W), cobalt (Co) and vanadium (V), and being products of decomposition reaction of the base material phase. In the production process, the constituent materials are treated thermally at a partially melting temperature in order to give the above-described novel structure to the oxide superconductor. Thus, the precipitation phases are dotted in a manner like islands in a sea of the base material phase being free from the grain boundaries, and the precipitation phases work as the pinning centers. Therefore, the oxide superconductor exhibits a high "Jc" value.

REFERENCES:
patent: 3932315 (1976-01-01), Sleight
patent: 4906609 (1990-03-01), Yamaguchi et al.
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Del Angel Vincente et al., "Effect of Silicon Carbide on the Properties of the Superconductor YBa.sub.2 Cu.sub.3 O.sub.7-.delta. ", Rev. Inst. Mex. Pet. 22(2), 109-12, 1990.
"Preparation of Y-Ba-Cu-O Superconductors With High Critical Current Density by Unidirectional Melt Solidificaiton", 362 Japanese Journal of Applied Physics 29 (1990) Feb., No. 2, Part 2, Tokyo, Japan.
"Variation of Composition in a Bi(Pb)-Sr-Ca-Cu-O Grain and the Influence of Mg and Ba Doping on Its Superconductivity", Japanese Japanese Journal of Applied Physics, vol.28, No. 7, Jul. 1989, pp. L 1140-L 1143.
"Improvement of Critical Current Density in YBa.sub.2 Cu.sub.3 O.sub.6+x Superconductor by Sn Addition", Japanese Journal of Applied Physics, vol. 29, No. 9, Sep. 1990, pp. L 1621-L 1623.
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