Oxidative secondary rhodium recovery process

Catalyst – solid sorbent – or support therefor: product or process – Regenerating or rehabilitating catalyst or sorbent – Treating with a liquid or treating in a liquid phase,...

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423 22, 502 28, 502 32, 562607, 562891, B01J 3868, B01J 3854, C01G 5500, C07C 5110

Patent

active

049450751

ABSTRACT:
Disclosed is a process for recovering rhodium catalyst values from "tars" formed during the preparation of acetic anhydride by the rhodium catalyzed carbonylation of a mixture of methyl iodide and methyl acetate and/or dimethyl ether. The disclosed process provides a means for the recovery of rhodium values which normally are not extracted from the tars by treating a methyl iodide solution of such tars with certain oxidants.

REFERENCES:
patent: 4388217 (1983-06-01), Hembre et al.
patent: 4434240 (1984-02-01), Pogach
patent: 4578368 (1986-03-01), Zoeller
patent: 4650649 (1987-03-01), Zoeller

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