Liquid purification or separation – Processes – Chemical treatment
Patent
1993-02-11
1993-12-28
Hruskoci, Peter
Liquid purification or separation
Processes
Chemical treatment
210760, 210763, 210904, C02F 178
Patent
active
052736636
ABSTRACT:
The oxidation of cyanide under acid conditions using oxygen as the oxidizing agent can be effected under mild reaction conditions when certain metal chelates are used as catalysts. Especially effective chelates are metal phthalocyanines, particularly where the metal is vanadium or a member of the iron group metals. The oxidation can be effected homogeneously using water soluble metal chelates, or can be performed heterogeneously, especially in a continuous fashion using a packed bed reactor, by using suitable water-insoluble metal chelates, especially when supported on appropriate carriers.
REFERENCES:
patent: 4537686 (1985-08-01), Borbely et al.
patent: 5120453 (1992-06-01), Frame et al.
patent: 5156748 (1992-10-01), Meunier et al.
R. Gierzatowicz et al., Effluent and Water Treatment Journal, 25, 26-31 (1986).
Chen et al. (Paper 81c presented at the 1990 AlChE Summer National Meeting, San Diego, California, Aug. 21, 1990).
Frame Robert R.
Kalnes Tom N.
Kurek Paul R.
Moser Mark D.
Hruskoci Peter
McBride Thomas K.
Snyder Eugene I.
UOP
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