Oxidative rearrangement of olefins

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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560174, 568910, 568900, 585639, C07C 4504

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active

042206049

ABSTRACT:
An isoolefin is converted to a ketone, e.g., isobutylene to methyl ethyl ketone, by an oxidative rearrangement in a two-phase diluent system in the presence of free oxygen, a suitable surfactant, and a catalyst system comprising palladium, copper, and an alkali or alkaline earth metal chloride.

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patent: 3668257 (1972-06-01), Schaeffer
patent: 3932521 (1976-01-01), Gloyer et al.
patent: 3944623 (1976-03-01), Chabardes et al.
patent: 3992432 (1976-11-01), Napier et al.
patent: 4152354 (1979-05-01), Stapp

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