Oxidative fluorination of phenols

Details Oxidative fluorination of phenols Oxidative fluorination of phenols

1975-02-06

1977-04-26

Thomas, Jr., James O.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260543H, 260505R, 260513R, 260586R, 260590PA, 260650F, 260648R, 260609R, 260470, C07C 4320

Patent

active

040201120

ABSTRACT:
Phenols are oxidatively fluorinated by reaction with sulfur tetrafluoride in hydrogen fluoride solution at about 0.degree. to 250.degree. C. to form products which are useful as solvents and/or plasticizers for polymers. The novel products of this process include 1-fluoro-2-hydro-2,5-cyclohexadienes of the structure ##STR1## WHERE A AND B ARE FLUORINE, OR TOGETHER ARE CARBONYL OXYGEN,

REFERENCES:
patent: 2859245 (1958-11-01), Smith
Hasek et al., J.A.C.S., vol. 82, pp. 543-551, (1960).
Reaktssii i metody issledsvannica organicheskukh, M.M. III emrkuha, pp. 40-63, (1971).

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