Oxidative denaturation of protein analytes

Chemistry: natural resins or derivatives; peptides or proteins; – Proteins – i.e. – more than 100 amino acid residues – Chemical modification or the reaction product thereof – e.g.,...

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530403, 530404, 530405, 530406, 530408, 530409, 530410, C07K 300, C07K 1300, C07K 1500, C07K 1700

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active

050617907

ABSTRACT:
A method for conferring or increasing the antigenicity of a disulfide-crosslinked protein by treating the protein with an oxidizing agent, such as periodate, having an oxidation potential sufficient to cleave disulfide linkages. Excess oxidizing agent is then inactivated by addition of a reducing agent. The resulting protein exhibits an increase in its ability to be bound by select antibodies, particularly monoclonal antibodies directed to linear peptide epitopes in the protein.

REFERENCES:
patent: 4033819 (1977-07-01), Helting
patent: 4658022 (1987-04-01), Knowles et al.
patent: 4683136 (1987-07-01), Milich et al.
patent: 4713366 (1987-12-01), Stevens

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