Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons

Details Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons

1987-07-01

1988-10-11

Davis, Curtis R.

Chemistry of hydrocarbon compounds

Unsaturated compound synthesis

Diolefin product

585443, 585658, C07C 509, C07C 5327

Patent

active

047773197

ABSTRACT:
Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons is carried out over metal vanadate catalysts under oxidizing conditions. The vanadate catalysts are represented by the formulas M.sub.3 (VO.sub.4).sub.2 and MV.sub.2 O.sub.6, M representing Mg, Zn, Ca, Pb, or Cd. The reaction is carried out in the presence of oxygen, but the formation of oxygenate by-products is suppressed.

REFERENCES:
patent: 4250346 (1981-02-01), Young et al.
patent: 4524236 (1985-06-01), McCain
patent: 4568790 (1986-02-01), McCain
patent: 4596787 (1986-06-01), Manyik et al.
patent: 4727208 (1988-02-01), King

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