Oxidative coupling process

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07C 2100

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040565742

ABSTRACT:
Isobutene is oxidatively coupled with vinylidene chloride by heating in the presence of palladium acetate, to give 1,1-dichloro-4-methylpenta-1,3-diene. This compound is useful as an intermediate in the production of insecticides. Any 1,1-dichloro-4-methylpenta-1,4-diene also produced is thermally isomerized to the 1,3 product.

REFERENCES:
patent: 3730957 (1973-05-01), Bozik et al.

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