Oxidative coupling of aliphatic and alicyclic hydrocarbons with

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By ring formation from nonring moiety – e.g. – aromatization,...

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585500, 585541, 585654, 585700, 585921, 585926, 585943, C07C 200

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049508270

ABSTRACT:
A catalyst and a process for oxidative coupling of aliphatic and alicyclic hydrocarbon compounds with aliphatic and alicyclic substituted aromatic hydrocarbon compounds to form a longer substituent hydrocarbon on the aromatic ring. The catalyst is mixed basic metal oxide catalyst, one preferred catalyst is boron/alkali metal promoted metal oxide. Reaction of methane with toluene and oxygen according to this invention results in conversion to styrene.

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