Oxidative carbonylation of alcohols to produce dialkyl oxalates

Details Oxidative carbonylation of alcohols to produce dialkyl oxalates Oxidative carbonylation of alcohols to produce dialkyl oxalates

1982-06-15

1985-06-11

Trousof, Natalie

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

502185, 502327, 560190, C07C 6736

Patent

active

045230293

ABSTRACT:
A process for the preparation of dialkyl oxalates by the oxidative carbonylation of alcohols which comprises reacting a mixture of carbon monoxide and oxygen with an alcohol in the presence of a heterogeneous catalyst comprising palladium and thallium on carbon.

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Fenton et al. II, J. Org. Chem., vol. 39, No. 5, (1974), pp. 701-704.

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