Oxidative alkoxycarbonylation of amines and amine derivatives

Details Oxidative alkoxycarbonylation of amines and amine derivatives Oxidative alkoxycarbonylation of amines and amine derivatives

1988-11-09

1989-10-24

Shippen, Michael L.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

560 24, 560 25, C07C125073

Patent

active

048763799

ABSTRACT:
The catalyzed oxidative alkoxycarbonylation of amines and substituted amines to form carbamates is disclosed. The process involves alkoxycarbonylation in the presence of a palladium-based catalyst using carbon monoxide, an alkanol and an oxygen-transer agent.

REFERENCES:
patent: 4178455 (1979-12-01), Hirai
patent: 4260781 (1981-04-01), Harvey
patent: 4297501 (1981-10-01), Becker
patent: 4304922 (1981-12-01), Becker
patent: 4582923 (1986-04-01), Stummann
patent: 4621149 (1986-11-01), Fukuoka

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