Oxidations using polyazamacrocycle metal complexes

Details Oxidations using polyazamacrocycle metal complexes Oxidations using polyazamacrocycle metal complexes

1993-12-10

1995-06-27

Ivy, C. Warren

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

549521, 549522, 549524, 549536, C07D30103, C07D30112

Patent

active

054281806

ABSTRACT:
A method is provided for oxidizing alkenes to epoxides by treating the alkene with a transition metal ion complex which includes a salen or salophen derivative and peroxymonosulfate ion or hypochlorite ion in a two phase system with a phase transfer catalyst, a water phase having a pH from about 6 to about 12.9 and an inorganic solvent phase in which the complex is sufficiently soluble.

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