Oxidation resistant organic hydrogen getters

Compositions – Getters or gas or vapor generating materials for electric... – Metal or metal compound containing

Reexamination Certificate

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C252S181300, C252S182310, C252S184000

Reexamination Certificate

active

07422701

ABSTRACT:
A composition for removing hydrogen from an atmosphere, comprising a mixture of a polyphenyl ether and a hydrogenation catalyst, preferably a precious metal catalyst, and most preferably Pt. This composition is stable in the presence of oxygen, will not polymerize or degrade upon exposure to temperatures in excess of 200° C., or prolonged exposure to temperatures in the range of 100-300° C. Moreover, these novel hydrogen getter materials can be used to efficiently removing hydrogen from mixtures of hydrogen/inert gas (e.g., He, Ar, N2), hydrogen/ammonia atmospheres, such as may be encountered in heat exchangers, and hydrogen/carbon dioxide atmospheres. Water vapor and common atmospheric gases have no adverse effect on the ability of these getter materials to absorb hydrogen.

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patent: 5624598 (1997-04-01), Shepodd et al.
patent: 5717014 (1998-02-01), Ohkawachi et al.
patent: 6018048 (2000-01-01), Morikawa et al.
patent: 6426314 (2002-07-01), Carroll et al.

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