Stock material or miscellaneous articles – All metal or with adjacent metals – Composite; i.e. – plural – adjacent – spatially distinct metal...
Reexamination Certificate
2001-02-26
2002-12-24
Jones, Deborah (Department: 1775)
Stock material or miscellaneous articles
All metal or with adjacent metals
Composite; i.e., plural, adjacent, spatially distinct metal...
C428S469000, C428S446000, C428S450000, C428S641000, C428S660000, C428S632000, C428S697000, C428S699000, C428S701000, C420S429000, C420S578000, C420S588000, C420S586100, C106S286800, C106S286400, C106S287100, C106S287180, C106S287190, C416S24100B
Reexamination Certificate
active
06497968
ABSTRACT:
BACKGROUND OF THE INVENTION
The present invention relates to turbine systems. More particularly, the invention relates to components of such turbine systems. Still more particularly, the invention relates to turbine components formed from a molybdenum silicide-based composite. Finally, the invention relates to environmentally resistant coatings for such turbine components.
Turbine systems, such as, but not limited to, aircraft turbines, land-based, turbines, marine-based turbines, and the like, and their components (hereinafter referred to as “turbine components”) have typically been formed from nickel (Ni) based materials, which are often referred to as Ni-based superalloys. Turbine components formed from these Ni-based superalloys exhibit desirable chemical and physical properties under the high temperature, high stress, and high-pressure conditions generally encountered during turbine operation. The highest surface temperatures of state-of-the-art jet engine turbine airfoils, for example, reach as high as about 2100° F. (about 1150° C.), or about 85% of the melting temperature (T
m
) of most of the Ni-based superalloys.
To date, the Ni-based superalloys have provided the desired level of performance for turbine system applications, causing the development of such Ni-based superalloys to be widely explored. As a result of such extensive study, the field has matured and few significant improvements have been realized in this area in recent years. In the meantime, efforts have been made to develop alternative turbine component materials.
These alternative materials include composite materials (hereinafter generally referred to as “molybdenum silicide-based composites”) that are based on molybdenum silicides, such as MoSi
2
, Mo
3
Si, Mo
5
Si
3
, and Mo
5
SiB
2
(T2) Most molybdenum silicide-based composites have melting temperatures of greater than about 3100° F. (about 1700° C.). If molybdenum silicide-based composites can be used at about 80% of their melting temperatures, they will have potential use in applications in which the temperature exceeds the current service temperature limit of Ni-based superalloys.
Molybdenum silicide-based composites comprising molybdenum (Mo), silicon (Si), and either boron (B) or chromium (Cr) are among the materials that have been proposed for turbine component applications in which Ni-based superalloys are presently used. These molybdenum silicide-based composites exhibit a high temperature capability which exceeds that of the Ni-based superalloys that are currently used in such applications. Exemplary molybdenum silicide-based composites are described by Berczik (U.S. Pat. Nos. 5,595,616 and 5,693,156), and Subramanian et al. (U.S. Pat. Nos. 5,505,793 and 5,683,524).
Although the molybdenum silicide-based composites show potential for use as next-generation turbine components having service temperatures that are significantly greater than those of current Ni-based superalloy components, the oxidation of such turbine components remains a concern. At temperatures in the range between about 2000° F. and about 2600° F. (between about 1090° C. and about 1425° C.), refractory materials can undergo rapid oxidation. While a slow-growing oxide scale can form on molybdenum silicide-based composites at this temperature, it is typically not a protective oxide scale. Another type of oxidation known as ‘pesting’ occurs at intermediate temperatures (e.g., between about 1000° F. and about 1800° F.). Pesting is a phenomenon that is characterized by the disintegration of a material into pieces or powders after exposure to air at intermediate temperatures. Refractory metals, particularly molybdenum, exhibit poor resistance to pesting oxidation.
While significant progress has been made in improving the oxidation performance of molybdenum silicide-based composites, it is desirable to provide coatings for turbine components fabricated from these materials in order to ensure long lifetimes at service temperatures of 2000° F. to 2600° F. Therefore, what is needed is a turbine system that includes components formed from molybdenum silicide-based composites, the components having coatings that will provide increased oxidation resistance at temperatures in the range between about 2000° F. and about 2600° F. What is further needed is a turbine system comprising molybdenum silicide-based composite components having coatings that will provide increased resistance to pesting at temperatures between about 1000° F. an about 1800° F. What is also needed is an environmentally resistant coating for molybdenum silicide-based composites, which will enhance oxidation resistance at high temperatures and pesting resistance at intermediate temperatures.
BRIEF SUMMARY OF THE INVENTION
The present invention meets these needs and others by providing a turbine system that includes molybdenum silicide-based composite components having coatings that increase oxidation resistance at high temperatures and resistance to pesting at intermediate temperatures. The present invention also provides an environmentally resistant coating for molybdenum silicide-based composites that exhibit improved oxidation resistance at high temperatures and resistance to pesting at intermediate temperatures. In addition, methods for making a coated molybdenum silicide-based composite turbine component and coating a molybdenum silicide-based composite are also disclosed.
Accordingly, one aspect of the present invention is to provide a turbine system having at least one turbine component, the component comprising: a molybdenum silicide-based composite substrate, the molybdenum silicide-based composite substrate comprising molybdenum, silicon, and at least one of chromium and boron; and an environmentally resistant coating disposed on a surface of the molybdenum silicide-based composite substrate. The environmentally resistant coating comprises silicon, titanium, chromium, and a balance of niobium and molybdenum.
A second aspect of the invention is to provide an environmentally resistant coating for a molybdenum silicide-based composite substrate. The environmentally resistant coating comprises: between about 43 and 67 atomic percent silicon; between about 2 and about 25 atomic percent titanium; between about 1 and about 25 atomic percent chromium; and a balance of niobium and molybdenum.
A third aspect of the invention is to provide a turbine system having at least one turbine component. The turbine component comprises: a molybdenum silicide-based composite substrate, the molybdenum silicide-based composite substrate comprising molybdenum, silicon, and at least one of chromium and boron; an environmentally resistant coating disposed on a surface of the molybdenum silicide-based composite substrate, the environmentally resistant coating comprising between about 43 and 67 atomic percent silicon, between about 2 and about 25 atomic percent titanium, between about 1 and about 25 atomic percent chromium, and a balance of niobium and molybdenum; and a thermal barrier coating disposed on an outer surface of the environmentally resistant coating.
A fourth aspect of the invention is to provide a method of making a turbine component comprising a molybdenum silicide-based composite and having an environmentally resistant coating, the environmentally resistant coating comprising between about 43 and 67 atomic percent silicon, between about 2 and about 25 atomic percent titanium, between about 1 and about 25 atomic percent chromium, and a balance of niobium and molybdenum. The method comprises the steps of: providing a molybdenum silicide-based composite substrate formed into the turbine component; and depositing the environmentally resistant coating onto the surface of the component.
A fifth aspect of the invention is to provide a method of coating a molybdenum-based substrate with an environmentally resistant coating, the environmentally resistant coating comprising between about 43 and 67 atomic percent silicon, between about 2 and about 25 atomic percent titanium, between about 1 and about 25 atomic percent chromium, and
Bewlay Bernard Patrick
Jackson Melvin Robert
Zhao Ji-Cheng
General Electric Company
Johnson Noreen C.
Jones Deborah
McNeil Jennifer
Santandrea Robert P.
LandOfFree
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