Oxidation resistant coatings for molybdenum

Stock material or miscellaneous articles – All metal or with adjacent metals – Having metal particles

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Details

428547, 428557, 428564, 428632, 428640, 416241R, B22F 504, B22F 702

Patent

active

047450339

ABSTRACT:
A molybdenum article is disclosed in which the substrate thereof has adherently bonded thereto a thermally self-healing plasma-sprayed coating consisting essentially of a composite of molybdenum and a refractory oxide material capable of reacting with molybdenum oxide under oxidizing conditions to form a substantially thermally stable refractory compound of molybdenum. The plasma-sprayed coating is formed of a plurality of interbonded plasma-sprayed layers of a composite of molybdenum/refractory oxide material produced from a particulate mixture thereof. The coating comprises a first layer of molybdenum plasma-sprayed bonded to the substrate of said molybdenum element and a second layer of plasma-sprayed mixture of particulate molybdenum/refractory oxide consisting essentially of predominantly molybdenum bonded to the first layer. The succeeding layers of the molybdenum/refractory oxide mixture provide from layer to layer a descending concentration gradient of molybdenum and a corresponding ascending concentration gradient of refractory oxide material. The concentration gradient continues to an N-1 layer in which the refractory oxide concentration of the mixture predominates and terminates at the Nth layer, the Nth layer consisting essentially of the refractory oxide material plasma-sprayed bonded to the N-1 layer.

REFERENCES:
patent: 3261673 (1966-07-01), Wheildon, Jr.
patent: 3340026 (1967-09-01), Kiwak
patent: 3719519 (1973-03-01), Perugini
patent: 3837817 (1974-09-01), Nakamura
patent: 3999954 (1976-12-01), Kolaska et al.
patent: 4485150 (1984-11-01), Tsuno
patent: 4612256 (1986-09-01), Neuhauser et al.

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