Oxidation of thiols to disulfides

Details Oxidation of thiols to disulfides Oxidation of thiols to disulfides

1973-12-26

1976-05-04

Jiles, Henry R.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

2603328, 260453RZ, 260545R, 260608, C07D33908

Patent

active

039548007

ABSTRACT:
A process for oxidizing alkyl thiols, cycloaliphatic thiols and aralkyl thiols or mixtures thereof to disulfides. The thiol reactant is oxidized by a sulfoxide reactant in the presence of a halogen-hydrogen halide catalyst. The catalysts for the reaction are iodine, hydrogen iodide, bromine, hydrogen bromide, chlorine, hydrogen chloride and mixtures thereof.

REFERENCES:
patent: 3376313 (1968-04-01), Wallace
patent: 3428671 (1969-02-01), Toland
patent: 3513088 (1970-05-01), Karabinos et al.

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