Oxidation of thiols employing cobalt molybdate/triethylamine cat

Details Oxidation of thiols employing cobalt molybdate/triethylamine cat Oxidation of thiols employing cobalt molybdate/triethylamine cat

1980-02-12

1981-09-08

Daus, Donald G.

Organic compounds -- part of the class 532-570 series

Organic compounds

Sulfur containing

C07C14912

Patent

active

042886279

ABSTRACT:
A thiol is oxidized to a corresponding disulfide employing a supported cobalt molybdate catalyst in combination with a liquid tertiary amine. 2-propanethiol is converted to diisopropyl disulfide with conversions of the order of 94% and selectivities of the order of 98%.

REFERENCES:
patent: 2574884 (1951-11-01), Mertz et al.
patent: 2651595 (1953-09-01), Moulthrop
patent: 3277180 (1966-10-01), Bapseres et al.
patent: 3299146 (1967-01-01), Gillette et al.
patent: 3308166 (1967-03-01), Biensan et al.
patent: 3565959 (1971-02-01), Lakase et al.
patent: 3978137 (1970-08-01), Frame
patent: 4090954 (1978-05-01), Ward
E. E. Reid, Organic Chemistry of Bivalent Sulfur, I, 28-29, 118-120, (1958).
J.A.C.S., 70, Dec. 1948, pp. 4143-4150.

Affiliated with

Also associated with

Rating

Oxidation of thiols employing cobalt molybdate/triethylamine cat does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Oxidation of thiols employing cobalt molybdate/triethylamine cat, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Oxidation of thiols employing cobalt molybdate/triethylamine cat will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-1193649