Oxidation of tertiary-alkyl substituted aromatics

Details Oxidation of tertiary-alkyl substituted aromatics Oxidation of tertiary-alkyl substituted aromatics

1990-01-31

1991-11-26

Dees, Jose G.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acids and salts thereof

502224, 562417, 562480, C07C 41265

Patent

active

050684078

ABSTRACT:
A process for the production of para-oriented dicarboxylic aromatic acids is disclosed in which an aromatic compound, having a tertiary alkyl group, is oxidized with molecular oxygen in the presence of a catalytic composition comprising a cobalt salt, a minor amount of a manganese salt, and a source of chloride in the presence of a solvent.

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patent: 3636082 (1972-01-01), Knowles
Sheldon and Kochi, "Metal-Catalyzed Oxidations of Organic Compounds", Academic Press, p. 316, (1981).
H. D. Holtz, J. Org. Chem., vol. 37, No. 13, pp. 2069-2074, (1972).

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