Oxidation of pyridine and derivatives

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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546348, 521 30, 521 33, 521 37, C07D21172, C07D21184, C07D21361, C07D21182

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active

058696784

ABSTRACT:
A process for preparing an N-oxide of pyridine or a halopyridine, said process comprising reacting a reaction mixture of said pyridine, or said halopyridine, and hydrogen peroxide in a reaction conducted at an elevated temperature in the presence of a catalytically effective amount of a heterogeneous catalyst, said heterogeneous catalyst being insoluble in said reactants, to form said 2-halopyridine-N-oxide or pyridine-N-oxide.

REFERENCES:
patent: 3047579 (1962-07-01), Witman
patent: 3203957 (1965-08-01), Kirchner
patent: 4504666 (1985-03-01), Earl
patent: 4585871 (1986-04-01), Boudakian
patent: 5082940 (1992-01-01), Legrand

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