Oxidation of phenol to p-benzoquinone in acetonitrile/methanol c

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07C 4608

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042579686

ABSTRACT:
An improved process for making p-benzoquinone by contacting phenol with an oxidant in the presence of a copper salt catalyst, the improvement which comprises employing a cosolvent system of acetonitrile and methanol, the weight ratio of acetonitrile to methanol being about 1 to 20:1.

REFERENCES:
patent: 3870731 (1975-05-01), Hutchings
patent: 3987068 (1976-10-01), Reilly

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