Oxidation of organic compounds having allylic or benzylic carbon

Details Oxidation of organic compounds having allylic or benzylic carbon Oxidation of organic compounds having allylic or benzylic carbon

1987-09-01

1992-12-15

Prescott, Arthur C.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acids and salts thereof

568309, 568426, 568910, C07C 5116

Patent

active

051718910

ABSTRACT:
The present invention is directed to a process of oxidizing organic compounds having allylic or benzylic carbon atoms. The process of this invention comprises reacting an organic compound having one or more allylic or benzylic carbon atoms with an effective amount of an effective oxidizing agent in water at a temperature equal to or greater than about 350.degree. C. and at a pressure equal to or greater than about 175 atmospheres, wherein said agent is selected from the group consisting of elemental sulfur, an oxidized form of elemental sulfur and, an organic or inorganic compound capable of forming elemental sulfur or said oxidized forms in situ under process conditions.

REFERENCES:
patent: 2900412 (1959-08-01), Toland, Jr.
patent: 2903480 (1959-09-01), Toland, Jr.

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