Oxidation of organic compounds by aqueous hypohalites using phas

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260348C, 260348R, 260413, 260465R, 2604651, 2604652, 260530R, 260566D, 260586P, 260591, 260593R, 260603C, C07C 4754, C07C 4976, C07C12000, C07C12010

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039962598

ABSTRACT:
Organic compounds oxidizable by hypohalite ion, such as amines, amides, primary and secondary alcohols, and alkanals are efficiently oxidized in a biphasic mixture comprising:
A. a water immiscible, liquid organic phase comprising an organic compound oxidizable by hypohalite ion; with
B. an aqueous phase containing hypohalite ion; and
C. a catalytic amount of a quaternary ammonium salt and/or a quaternary phosphonium salt.

REFERENCES:
starks, J. Amer. Chem. Soc., vol. 93, 195-199 (1971).
Starks et al, Chemical Abstracts, vol. 72, 115271t (1970).

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