Oxidation of methane over heterogeneous catalysts

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis

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585700, 585541, 585654, 585658, 585661, 585943, C07C 200

Patent

active

053368266

ABSTRACT:
Higher hydrocarbons are produced from methane by reacting the methane at elevated temperature, suitably in the range from 600.degree. to 800.degree. C., with an oxygen-containing gas having a ratio of methane to oxygen of greater than the stoichiometric ratio for complete combustion in the presence as catalyst of a lithium-doped material which under the reaction conditions is a physically base-stable, non-melting, oxygen-stable compound of an element of Groups III to VIII of the Periodic Table of the Elements including the rare earth elements.

REFERENCES:
patent: 4450313 (1984-05-01), Eastman
patent: 4476344 (1984-10-01), Kimble
patent: 4523049 (1985-06-01), Jones et al.
patent: 4650781 (1987-03-01), Jones et al.
patent: 4658077 (1987-04-01), Kolts

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