Oxidation of hydrocarbons over ordered arrays of heteropolyacids

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568399, 5689105, C07C 2712, C07C 3112, C07C 4533

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active

053347803

ABSTRACT:
Alkanes are catalytically oxidized using heteropolyacids (HPAs) or polyoxoanions (POAs) deposited on a graphite surface. The HPAs and POAs are framework-substituted with a different metal in place of a metal-oxygen unit.

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Ai, "Partial Oxidation of n-Butane with Heteropoly Compound-based Catalysts," Proc. 8th Intern. Cong. Catalysis, Berlin, 1984 Verlag Chemie, 5,475-486.
Lyons et al., "Active Iron Oxo Centers for the Selective Catalytic Oxidation of Alkanes," Structure-Activity and Selectivity Relationships in Heterogeneous Catalysis, 99-116 (1991) Amsterdam.
Watson et al, "Scanning Tunneling Microscopy of Ordered Hetero and Isopolyanion Arrays on Graphite", Langmuir, 8, 1145-1148 (1992).

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