Oxidation of dimercaptans to organic disulfide polymers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From sulfur-containing reactant

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528375, C08G 7504

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active

055457142

ABSTRACT:
A process for preparing an organic disulfide polymer such as polyethylene disulfide which is used in batteries comprises contacting a dimercaptan such as 1,2-ethanedithiol with elemental sulfur using a mixture of a basic compound such as NaOH and an ethoxylated alcohol such as Union Carbide's TERGITOL.RTM. 15-S-7 having the formula of R.sup.2 O(CH.sub.2 CH.sub.2 O).sub.7 H as catalyst wherein the dimercaptan is present in excess amount to effect the preparation of the disulfide polymer.

REFERENCES:
patent: 3625925 (1971-12-01), Oswald
patent: 4163832 (1979-08-01), Oswald
patent: 5206439 (1993-04-01), Shaw
patent: 5232623 (1993-08-01), Shaw
patent: 5283368 (1994-02-01), Shaw
Tanaka et al. Tetrahedron, 44(11), 3241-3249, 1988.

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