Oxidation method of primary or secondary alcohol

Details Oxidation method of primary or secondary alcohol Oxidation method of primary or secondary alcohol

2007-04-24

2007-04-24

Witherspoon, Sikarl A. (Department: 1621)

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

C568S361000, C568S402000, C568S431000, C568S471000

Reexamination Certificate

active

11290474

ABSTRACT:
A method for preparing an aldehyde or ketone by oxidizing a primary or secondary alcohol in the presence of a nitroxyl radical compound and a co-oxidant in an organic solvent, which process is characterized in using an organic N-bromoamide compound or a combination of N-chlorosuccinimide and a compound having bromide ion as the co-oxidant.

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Anelli, P. C. et al., “Fast and Selective Oxidation of Primary Alcohols to Aldehydes or to Carboxylic Acids and of Secondary Alcohols to Ketones Mediated by Oxoammonium Salts under Two-Phase Conditions”,J. Org. Chem., vol. 52, pp. 2559 to 2562 (1987).
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