Osmium catalyzed organic hydroperoxide hydroxylation of olefinic

Details Osmium catalyzed organic hydroperoxide hydroxylation of olefinic Osmium catalyzed organic hydroperoxide hydroxylation of olefinic

1975-10-07

1977-09-20

Evans, Joseph E.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260413, 2603463, C07D30789, C11C 100, C07C 2902

Patent

active

040497240

ABSTRACT:
Method for preparing polyols such as diols and triols by the homogeneous catalytic hydroxylation of an olefinic compound by contacting the olefinic compound with an organic hydroperoxide in an aqueous solution at an initial pH above 8 in the presence of a catalytic amount of a water soluble osmium compound as the catalyst.

REFERENCES:
patent: 2437648 (1948-03-01), Milas
patent: 2773101 (1956-12-01), Smith et al.
patent: 2813130 (1957-11-01), Keeler et al.
patent: 2833787 (1958-05-01), Carlson et al.
patent: 3317592 (1967-05-01), Maclean et al.
patent: 3488394 (1970-01-01), Cummins

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